Class 11Chemistry3 Organic Chemistry: Purification and CharacterisationChemical analysis of organic compounds
MediumAssertion : During the test for nitrogen with Lassaigne's extract,on adding $FeCl_3$ solution,sometimes a blood-red coloration is obtained.
Reason : Sulphur is also present along with nitrogen in the organic compound.
Reason : Sulphur is also present along with nitrogen in the organic compound.
- AIf both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
- BIf both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
- CIf the Assertion is correct but Reason is incorrect.
- DIf both the Assertion and Reason are incorrect.
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Similar Questions
Which of the following compounds is added to the sodium extract before the addition of silver nitrate for the testing of halogens?
Which of the following substances gives a red color when its $Lassaigne's$ extract is treated with alkali and ferric chloride?
Easy
View SolutionThe Lassaigne's extract is boiled with conc. $HNO_3$ while testing for halogens. By doing so it
MediumAIPMT 2011
View SolutionMatch the compounds in Column $I$ with their characteristic test$(s)$ reaction$(s)$ given in Column $II$.
Column $I$ Column $II$ $A. H_2N-NH_3^+Cl^-$ $p. \text{Sodium fusion extract of the compound gives Prussian blue colour with } FeSO_4$ $B. HO-C_6H_4-CH(NH_3^+)COOH \text{ (with } I^- \text{ counterion)}$ $q. \text{Gives positive } FeCl_3 \text{ test}$ $C. HO-C_6H_4-NH_3^+Cl^-$ $r. \text{Gives white precipitate with } AgNO_3$ $D. (NO_2)_2C_6H_3-NH-NH_3^+Br^-$ $s. \text{Reacts with aldehydes to form the corresponding hydrazone derivative}$
| Column $I$ | Column $II$ |
|---|---|
| $A. H_2N-NH_3^+Cl^-$ | $p. \text{Sodium fusion extract of the compound gives Prussian blue colour with } FeSO_4$ |
| $B. HO-C_6H_4-CH(NH_3^+)COOH \text{ (with } I^- \text{ counterion)}$ | $q. \text{Gives positive } FeCl_3 \text{ test}$ |
| $C. HO-C_6H_4-NH_3^+Cl^-$ | $r. \text{Gives white precipitate with } AgNO_3$ |
| $D. (NO_2)_2C_6H_3-NH-NH_3^+Br^-$ | $s. \text{Reacts with aldehydes to form the corresponding hydrazone derivative}$ |
What happens to the halogen when $AgNO_3$ is added to the Lassaigne solution acidified with $HNO_3$?
Easy
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