Assertion (A): Chlorobenzene is not formed in | vedclass

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(A) The reaction of alcohols with $SOCl_2$ proceeds via an $S_N2$ mechanism or $S_Ni$ mechanism to replace the $-OH$ group with $-Cl$.In phenol,the lo

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$(A)$ and $(R)$ are correct. $(R)$ is the correct explanation of $(A)$

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(A) The reaction of alcohols with $SOCl_2$ proceeds via an $S_N2$ mechanism or $S_Ni$ mechanism to replace the $-OH$ group with $-Cl$.In phenol,the lone pair of electrons on the oxygen atom participates in resonance with the benzene ring,giving the $C-O$ bond a partial double bond character.This makes the $C-O$ bond stronger and shorter,preventing the cleavage of the $C-O$ bond required to replace the $-OH$ group with $-Cl$.Therefore,chlorobenzene is not formed when phenol reacts with $SOCl_2$.Both Assertion $(A)$ and Reason $(R)$ are correct,and $(R)$ is the correct explanation of $(A)$.

Assertion $(A)$: Chlorobenzene is not formed in the reaction of phenol with thionyl chloride.
Reason $(R)$: In phenol,the carbon-oxygen bond has partial double bond character.
The correct answer is

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Assertion $(A)$: Chlorobenzene is not formed in the reaction of phenol with thionyl chloride.Reason $(R)$: In phenol,the carbon-oxygen bond has partial double bond character.The correct answer is