At $600\ ^{\circ}C$,$NH_4COONH_2\ (s) \rightleftharpoons 2NH_3\ (g) + CO_2\ (g)$ has an equilibrium constant $K_p = 3.2 \times 10^2\ bar^3$. Calculate $K_c$. $\left( R = 0.082\ L\ atm\ K^{-1}\ mol^{-1} \right)$

  • A
    $1.2 \times 10^{-5}$
  • B
    $1.5 \times 10^{-4}$
  • C
    $2.1 \times 10^{-6}$
  • D
    $3.4 \times 10^{-5}$

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The value of $K_{p}$ for the reaction,$CO_{2(g)} + C_{(s)} \rightleftharpoons 2CO_{(g)}$ is $3.0$ at $1000 \ K$. If initially $P_{CO_{2}} = 0.48 \ bar$ and $P_{CO} = 0 \ bar$ and pure graphite is present,calculate the equilibrium partial pressures of $CO$ and $CO_{2}$.

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