At $25^{\circ} C$ and $1 \, atm$ pressure,the enthalpy of combustion of benzene$_{(l)}$ and acetylene$_{(g)}$ are $-3268 \, kJ \, mol^{-1}$ and $-1300 \, kJ \, mol^{-1}$,respectively. The change in enthalpy for the reaction $3 C_2H_{2(g)} \rightarrow C_6H_{6(l)}$ is $..... \, kJ \, mol^{-1}$.

The amount of heat released when $20 \ mL$ of $0.5 \ M$ $NaOH$ is mixed with $100 \ mL$ of $0.1 \ M$ $HCl$ is $x \ kJ$. The heat of neutralization is:

Match the following items in List-$I$ with their corresponding expressions in List-$II$.

List-$I$	List-$II$
$A$. At constant volume the change in internal energy of a system	$I$. $W = -2.303 nRT \log \frac{V_f}{V_i}$
$B$. Isothermal irreversible change	$II$. $W_{adiabatic} = \Delta U$
$C$. Isothermal reversible change	$III$. $q_V = \Delta U$
$D$. Adiabatic change	$IV$. $W = -p_{ex} (V_f - V_i)$
	$V$. $\Delta U = \Delta H - \Delta nRT$

Calculate the heat produced in $kJ$ when $280 \ g$ of $CaO$ is completely converted to $CaCO_3$ by reaction with $CO_2$ at $27 \ ^{\circ}C$ and at constant volume :-
(Given) $\Delta H^o_f (CaCO_3, s) = -1207 \ kJ/mol$
$\Delta H^o_f (CaO, s) = -635 \ kJ/mol$
$\Delta H^o_f (CO_2, g) = -394 \ kJ/mol$ (in $kJ$)

$200 \ mL$ of $0.2 \ M \ HCl$ is mixed with $300 \ mL$ of $0.1 \ M \ NaOH$. The molar heat of neutralization of this reaction is $-57.1 \ kJ \ mol^{-1}$. The increase in temperature in $^{\circ}C$ of the system on mixing is $x \times 10^{-2}$. The value of $x$ is ....... . (Nearest integer)
[Given : Specific heat of water $= 4.18 \ J \ g^{-1} \ K^{-1}$
Density of water $= 1.00 \ g \ cm^{-3}$]
(Assume no volume change on mixing)

The enthalpy of sublimation of $I_{2(s)}$ is $57.3 \, kJ \, mol^{-1}$ and the enthalpy of fusion is $15.5 \, kJ \, mol^{-1}$. The enthalpy of vaporization of $I_2$ is ..................... $kJ \, mol^{-1}$. (in $.8$)