Benzoic acid has a higher molecular weight in benzene and a lower molecular weight in water because:

  • A
    Water has a lower freezing point and a higher boiling point than benzene.
  • B
    It dissociates to a greater extent in benzene than in water.
  • C
    It associates in water and dissociates in benzene.
  • D
    It dissociates in water and associates in benzene.

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$A$ solute $A$ dimerizes in water. The boiling point of a $2 \, M$ solution of $A$ is $100.52^{\circ} C$. The percentage association of $A$ is ..... $\%$.
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When $1.0 \ g$ of $KCl$ is dissolved in $200 \ g$ water,the decrease in freezing point of such solution is $0.24 \ K$,calculate Van't Hoff factor $(i)$ for such solution. $K_f$ of water $=$ $1.86 \ K \ kg \ mol^{-1}$.

The Van't Hoff factor of $BaCl_2$ at a concentration of $0.01 \ M$ is $1.98$. The percentage dissociation of $BaCl_2$ at this concentration will be: (in $\%$)

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When $0.0106 \text{ mole}$ of acetic acid is dissolved in $1 \text{ kg}$ of water, the observed freezing point depression is $0.0205 \text{ K}$. If the calculated freezing point depression is $0.0197 \text{ K}$, the Van't Hoff factor $(i)$ and the degree of dissociation $(\alpha)$ of acetic acid are respectively:

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