Calculate the heat of formation of $PCl_{5(s)}$ from the following data:
$2P_{(s)} + 3Cl_{2(g)} \to 2PCl_{3(l)}; \Delta H_1 = -151.8 \ kcal$
$PCl_{3(l)} + Cl_{2(g)} \to PCl_{5(s)}; \Delta H_2 = -32.8 \ kcal$
Determine the enthalpy of formation for $PCl_{5(s)}$ in $kcal$.

The standard enthalpy of formation of $H_2O_{(g)}$ at $298 \ K$ is $-241.82 \ kJ \ mol^{-1}$. Calculate the enthalpy of formation of $H_2O_{(g)}$ at $373 \ K$,assuming $C_p$ is independent of temperature.
$C_p$ of $H_2O_{(g)} = 33.58 \ J \ K^{-1} \ mol^{-1}$
$C_p$ of $H_{2(g)} = 28.84 \ J \ K^{-1} \ mol^{-1}$
$C_p$ of $O_{2(g)} = 29.37 \ J \ K^{-1} \ mol^{-1}$

From the following thermochemical equations,find out the heat of ionisation $Z$ for a weak acid $HA$:
$HA \to A^{-} + H^{+} , \Delta H = Z$
$H^{+} + OH^{-} \to H_2O , \Delta H = X$
$HA + OH^{-} \to A^{-} + H_2O , \Delta H = Y$

From the given reaction,$N_{2(g)} + 3H_{2(g)} \longrightarrow 2NH_{3(g)} \quad \Delta H = -92.6 \ kJ$,the enthalpy of formation of $NH_3$ is (in $kJ$):

If the enthalpy of combustion of carbon to $CO_{2(g)}$ is $-394.0 \ kJ \ mol^{-1}$,the enthalpy change for the formation of $17.6 \ g$ of $CO_2$ from carbon and dioxygen at the same temperature in $kJ$ is:

The heat released when $0.8 \, g$ of carbon is converted to carbon dioxide is $x \, cal$. The heat released when $0.8 \, g$ of carbon is converted to carbon monoxide is $y \, cal$. If $x > y$,then the heat released when $1.86 \, g$ of carbon monoxide is converted to carbon dioxide will be: