Calculate the work done for the following reaction at $27^{\circ}C$: $C_2H_4(g) + H_2(g) \rightarrow C_2H_6(g)$ $(R = 8.314 \text{ J K}^{-1} \text{mol}^{-1})$ (in $\text{ J}$)

Benzene burns according to the following equation at $300 \ K$ $(R = 8.314 \ J \ mol^{-1} K^{-1})$: $2 C_6H_{6(l)} + 15 O_{2(g)} \to 12 CO_{2(g)} + 6 H_2O_{(l)}$,$\Delta H^o = -6542 \ kJ/mol$. What is the $\Delta E^o$ for the combustion of $1.5 \ mol$ of benzene in $kJ$?

For the reaction $X_2O_{4(g)} \to 2XO_{2(g)}$,given $\Delta U = 2.1 \, kcal$ and $\Delta S = 20 \, cal \, K^{-1}$ at $300 \, K$. Calculate $\Delta G$ in $kcal$.

An ideal gas is allowed to expand both reversibly and irreversibly in an isolated system. If $T_i$ is the initial temperature and $T_f$ is the final temperature,which of the following statements is correct?

$A$ fish swimming in a water body,when taken out,is covered with a film of water of weight $36 \ g$. When it is subjected to cooking at $100^{\circ} C$,the internal energy change for vaporization in $kJ \ mol^{-1}$ is $......$ [nearest integer].
[Assume steam to be an ideal gas. Given $\Delta_{vap} H^{\ominus}$ for water at $373 \ K$ and $1 \ bar$ is $41.1 \ kJ \ mol^{-1}$; $R = 8.31 \ J \ K^{-1} \ mol^{-1}$]

The value of $\Delta H_{transition}$ for $C(\text{graphite}) \rightarrow C(\text{diamond})$ is $1.9 \ kJ/mol$ at $25^{\circ}C$. The entropy of graphite is higher than the entropy of diamond. This implies that which of the following is incorrect $:-$