Calculate:
$(a)$ $\Delta G^{\circ}$ and
$(b)$ the equilibrium constant for the formation of $NO_2$ from $NO$ and $O_2$ at $298 \, K$
$NO_{(g)} + 1/2 O_{2(g)} \longleftrightarrow NO_{2(g)}$
Given:
$\Delta G^{\circ}_f(NO_2) = 52.0 \, kJ/mol$
$\Delta G^{\circ}_f(NO) = 87.0 \, kJ/mol$
$\Delta G^{\circ}_f(O_2) = 0 \, kJ/mol$

Vedclass pdf generator app on play store
Vedclass iOS app on app store
$(a)$ For the given reaction,
$\Delta G^{\circ} = \Delta G^{\circ}_f(\text{Products}) - \Delta G^{\circ}_f(\text{Reactants})$
$\Delta G^{\circ} = 52.0 - \{87.0 + 0\} = -35.0 \, kJ \, mol^{-1}$
$(b)$ We know that,
$\Delta G^{\circ} = -2.303 \, RT \, \log K_c$
$\log K_c = \frac{-\Delta G^{\circ}}{2.303 \, RT}$
$\log K_c = \frac{-(-35.0 \times 10^3 \, J \, mol^{-1})}{2.303 \times 8.314 \, J \, K^{-1} \, mol^{-1} \times 298 \, K}$
$\log K_c = 6.134$
$\therefore K_c = \text{antilog}(6.134) = 1.36 \times 10^6$
Hence,the equilibrium constant for the given reaction $K_c$ is $1.36 \times 10^6$.

Explore More

Similar Questions

For the equilibrium:
$CaCO_{3(s)} \rightleftharpoons CaO_{(s)} + CO_{2(g)}$; $K_{p} = 1.64 \ atm$ at $1000 \ K$.
$50 \ g$ of $CaCO_{3}$ in a $10 \ L$ closed vessel is heated to $1000 \ K$. The percentage of $CaCO_{3}$ that remains unreacted at equilibrium is:
(Given $R = 0.082 \ L \ atm \ K^{-1} \ mol^{-1}$)

Consider the following reaction equilibrium:
$N_{2(g)} + 3H_{2(g)} \rightleftharpoons 2NH_{3(g)}$
Initially,$1 \ mol$ of $N_2$ and $3 \ mol$ of $H_2$ are taken in a $2 \ L$ flask. At equilibrium,if the number of moles of $N_2$ is $0.6$,what is the total number of moles of all gases present in the flask?

$6.9 \ g$ of $N_2O_4$ is taken in a $0.5 \ L$ closed vessel at $400 \ K$. For the equilibrium $N_2O_{4(g)} \rightleftharpoons 2NO_{2(g)}$,the total pressure at equilibrium is $9.15 \ atm$. Calculate $K_c$,$K_p$,and the partial pressure of each component.

For the gas phase reaction; $C_2H_{4(g)} + H_{2(g)} \rightleftharpoons C_2H_{6(g)}$,$\Delta H = -32.7 \ kcal$ carried out in a vessel,the equilibrium concentration of $C_2H_4$ can be increased by:

For the equilibrium $2SO_{2(g)} + O_{2(g)} \rightleftharpoons 2SO_{3(g)}$,the partial pressures of $SO_2$,$O_2$,and $SO_3$ are $0.662 \ atm$,$0.101 \ atm$,and $0.331 \ atm$ respectively. If the equilibrium concentrations of $SO_2$ and $SO_3$ are made equal,the partial pressure of $O_2$ will be ..... $atm$.

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo