Check whether the following statements are true or false:
$1.$ The change in internal energy $\Delta U = 0$ in a cyclic process.
$2.$ In an adiabatic process,temperature remains constant.
$3.$ The internal energy of a system during an isothermal process decreases.

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(A) $1.$ True. In a cyclic process,the system returns to its initial state,so the change in state functions like internal energy is zero $(\Delta U = 0)$.
$2.$ False. In an adiabatic process,there is no exchange of heat $(Q = 0)$,but the temperature of the system changes as work is done.
$3.$ False. In an isothermal process,the temperature remains constant. Since internal energy of an ideal gas depends only on temperature,$\Delta U = 0$ for an isothermal process.

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When a system is taken from state $i$ to state $f$ along the path $iaf$,$Q = 50 \ J$ and $W = 20 \ J$. Along the path $ibf$,$Q = 35 \ J$ and $W = -13 \ J$. For the curved path $fi$,$Q = \dots \ J$.

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In the figure,a container is shown to have a movable (frictionless) piston on top. The container and the piston are made of perfectly insulating material,allowing no heat transfer between the outside and inside. The container is divided into two compartments by a rigid partition made of a thermally conducting material that allows slow heat transfer. The lower compartment is filled with $2$ moles of an ideal monatomic gas at $700 \ K$,and the upper compartment is filled with $2$ moles of an ideal diatomic gas at $400 \ K$. The heat capacities per mole are: for monatomic gas,$C_v = \frac{3}{2} R, C_p = \frac{5}{2} R$; for diatomic gas,$C_v = \frac{5}{2} R, C_p = \frac{7}{2} R$.
$1.$ Consider the partition to be rigidly fixed so that it does not move. When equilibrium is achieved,the final temperature of the gases will be:
$(A) 550 \ K$ $(B) 525 \ K$ $(C) 513 \ K$ $(D) 490 \ K$
$2.$ Now consider the partition to be free to move without friction so that the pressure of gases in both compartments is the same. Then the total work done by the gases until they achieve equilibrium will be:
$(A) 250 \ R$ $(B) 200 \ R$ $(C) 100 \ R$ $(D) -100 \ R$
Give the answer for questions $1$ and $2$.

Which of the following is correct in terms of increasing work done for the same initial and final state?

Three samples $X, Y$,and $Z$ of the same gas have equal volumes and temperatures. The volume of each sample is doubled. The process is isothermal for $X$,adiabatic for $Y$,and isobaric for $Z$. If the final pressures are equal for the three samples,find the ratio of the initial pressures. (Take adiabatic exponent $\gamma = 3/2$)

$A$ gas is enclosed in a cylinder with a movable frictionless piston. Its initial thermodynamic state at pressure $P_i = 10^5 \text{ Pa}$ and volume $V_i = 10^{-3} \text{ m}^3$ changes to a final state at $P_f = (1/32) \times 10^5 \text{ Pa}$ and $V_f = 8 \times 10^{-3} \text{ m}^3$ in an adiabatic quasi-static process, such that $P^3 V^5 = \text{constant}$. Consider another thermodynamic process that brings the system from the same initial state to the same final state in two steps: an isobaric expansion at $P_i$, followed by an isochoric (isovolumetric) process at volume $V_f$. The amount of heat supplied to the system in the two-step process is approximately: (in $\text{ J}$)

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