Choose the correct statement$(s)$ among the following:
$(A)$ $[FeCl_4]^-$ has tetrahedral geometry.
$(B)$ $[Co(en)(NH_3)_2Cl_2]^+$ has $2$ geometrical isomers.
$(C)$ $[FeCl_4]^-$ has higher spin-only magnetic moment than $[Co(en)(NH_3)_2Cl_2]^+$.
$(D)$ The cobalt ion in $[Co(en)(NH_3)_2Cl_2]^+$ has $sp^3d^2$ hybridization.

Match the complexes in Column-$I$ with their properties listed in Column-$II$.

Column-$I$	Column-$II$
$A$. $[Co(NH_3)_4(H_2O)_2]Cl_2$	$p$. geometrical isomers
$B$. $[Pt(NH_3)_2Cl_2]$	$q$. paramagnetic
$C$. $[Co(H_2O)_5Cl]Cl$	$r$. diamagnetic
$D$. $[Ni(H_2O)_6]Cl_2$	$s$. metal ion with $+2$ oxidation state

Which of the following change the colour of the aqueous solution of $FeCl_3$?

Select the correct code about complex $[Cr(NO_2)(NH_3)_5][ZnCl_4]$:
$(I)$ $IUPAC$ name of compound is pentaamminenitrito$-N$-chromium$(III)$ tetrachlorozincate$(II)$
$(II)$ It shows geometrical isomerism
$(III)$ It shows linkage isomerism
$(IV)$ It shows coordination isomerism

Some statements are given below $-$
$(a)$ Coordination compounds $[Pt(NH_3)_3(NCS)]$ and $[Pt(NH_3)_3(SCN)]$ are examples of linkage isomerism.
$(b)$ In the coordination compound $K_4[Ni(CN)_4]$, the oxidation state of nickel is zero.
$(c)$ The hybridization, shape and magnetic moment of $K_3[Cu(CN)_4]$ are respectively $dsp^2$, square planar, $1.73 \ B.M.$
$(d)$ $[Cr(NCS)(NH_3)_5][ZnCl_4]$ exhibits only linkage isomerism.

$1\,L, 0.02\,M$ solution of $[Co(NH_3)_5SO_4]Br$ is mixed with $1\,L, 0.02\,M$ solution of $[Co(NH_3)_5Br]SO_4$. The resulting solution is divided into two equal parts $(X)$ and treated with excess $AgNO_3$ solution and $BaCl_2$ solution respectively as shown below:
$1\,L$ Solution $(X) + AgNO_3$ solution (excess) $\rightarrow Y$
$1\,L$ Solution $(X) + BaCl_2$ solution (excess) $\rightarrow Z$
The number of moles of $Y$ and $Z$ respectively are: