Consider the following complexes:
$(a) \ Na_2[Fe(CN)_5NO]$
$(b) \ [Fe(H_2O)_5NO]SO_4$
$(c) \ K_4[Fe(CN)_6]$
Which of the following statements is wrong?

  • A
    $(a)$ is used in the detection of $S^{2-}$ ions.
  • B
    The complex part of each compound is octahedral.
  • C
    $(c)$ is used in the detection of $Fe^{3+}$ ions.
  • D
    The oxidation state $(O.S.)$ of $Fe$ in $(a)$ and $(b)$ is $+1$.

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The correct statements from the following are:
$A$. The strength of anionic ligands can be explained by crystal field theory.
$B$. Valence bond theory does not give a quantitative interpretation of kinetic stability of coordination compounds.
$C$. The hybridization involved in the formation of $\left[Ni(CN)_4\right]^{2-}$ complex is $dsp^2$.
$D$. The number of possible isomer$(s)$ of $cis-\left[PtCl_2(en)_2\right]^{2+}$ is one.
Choose the correct answer from the options given below:

$CuSO_{4(aq)}$ $\xrightarrow{H_2S \uparrow} M \downarrow$ $\xrightarrow[\text{Excess}]{KCN} N + O$
Then final products $N$ and $O$ are respectively.

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When potassium iodide is added to an aqueous solution of potassium ferricyanide,a reversible reaction is observed in which a complex $P$ is formed. In a strong acidic medium,the equilibrium shifts completely towards $P$. Addition of zinc chloride to $P$ in a slightly acidic medium results in a sparingly soluble complex $Q$.
$(1)$ The number of moles of potassium iodide required to produce two moles of $P$ is. . .
$(2)$ The number of zinc ions present in the molecular formula of $Q$ is. . . .
Give the answer for $(1)$ and $(2)$.

The complex ion $[Co(en)_2Br_2]^+$ has two optical isomers. Their correct configurations are:

Consider the following reaction and identify the correct statement:
$[M(gly)_2(NH_3)_2]^+ \xrightarrow[-2NH_3]{+gly} [M(gly)_3]$

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