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What is the correct order of stability for $1^\circ, 2^\circ, 3^\circ$ carbocations and benzyl carbocation?

Rank the transition states that occur during the following reaction steps in order of increasing stability (least $\to$ most stable):
$1. CH_3-OH_2^+ \to CH_3^+ + H_2O$
$2. (CH_3)_3C-OH_2^+ \to (CH_3)_3C^+ + H_2O$
$3. (CH_3)_2CH-OH_2^+ \to (CH_3)_2CH^+ + H_2O$

What is homolytic cleavage of a covalent bond? Explain with an example. Or,write about bond cleavage and the intermediate free radical.

Which of the following compounds forms the most stable carbocation: $(CH_3)_3C-Br$,$(C_6H_5)_3CBr$,$(C_6H_5)_2CHBr$,and $C_6H_5CH_2Br$?

Which of the following carbocations is expected to be most stable?

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