Consider the cell $Pt | H_2(P_1 \ atm) | H^{+}(X_1 \ M) || H^{+}(X_2 \ M) | H_2(P_2 \ atm) | Pt$. The cell reaction will be spontaneous if

  • A
    $P_1 = P_2$ and $X_1 > X_2$
  • B
    $P_1 = P_2$ and $X_1 = X_2$
  • C
    $X_1 = X_2$ and $P_1 > P_2$
  • D
    $X_1 = X_2$ and $P_1 < P_2$

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The electrode potential of the following half cell at $298 \ K$ is given by the cell reaction:
$X | X^{2+}(0.001 \ M) || Y^{2+}(0.01 \ M) | Y$
The cell potential is $....... \times 10^{-2} \ V$ (Nearest integer).
Given: $E^0_{X^{2+} | X} = -2.36 \ V$,$E^0_{Y^{2+} | Y} = +0.36 \ V$,$\frac{2.303 \ RT}{F} = 0.06 \ V$.

The equilibrium constant of the reaction $Cu_{(s)} + 2Ag^{+}_{(aq)} \to Cu^{2+}_{(aq)} + 2Ag_{(s)}$ with $E^{\circ} = 0.46 \ V$ at $298 \ K$ is approximately:

The pressure of hydrogen gas is increased from $1 \, atm$ to $100 \, atm$ keeping the $[H^+]$ constant at $1 \, M$. The potential of the hydrogen half-cell at $25 \, ^\circ C$ will be .......... $V$.

What is $E_{cell}$ (in $V$) of the following cell at $298 \ K$ ?
$(E^{\ominus}_{Zn^{2+}/Zn} = -0.76 \ V ; E^{\ominus}_{Ni^{2+}/Ni} = -0.25 \ V ; \frac{2.303 RT}{F} = 0.06 \ V)$
$Zn_{(s)} | Zn^{2+} (0.01 \ M) || Ni^{2+} (0.1 \ M) | Ni_{(s)}$

The potential of a hydrogen electrode at $pH = 10$ is (in $V$)

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