Consider the following gaseous equilibria with equilibrium constants $K_{1}$ and $K_{2}$ respectively:
$SO_{2(g)} + \frac{1}{2} O_{2(g)} \rightleftharpoons SO_{3(g)}$
$2 SO_{3(g)} \rightleftharpoons 2 SO_{2(g)} + O_{2(g)}$
The equilibrium constants are related as:

  • A
    $2 K_{1} = K_{2}^{2}$
  • B
    $K_{1}^{2} = \frac{1}{K_{2}}$
  • C
    $K_{2}^{2} = \frac{1}{K_{1}}$
  • D
    $K_{2} = \frac{2}{K_{1}^{2}}$

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$PCl_5$,$PCl_3$,and $Cl_2$ are at equilibrium at $500 \ K$ with concentrations $[PCl_3] = 1.59 \ M$,$[Cl_2] = 1.59 \ M$,and $[PCl_5] = 1.41 \ M$. Calculate $K_c$ for the reaction:
$PCl_5 \rightleftharpoons PCl_3 + Cl_2$

For the reaction $2H_2S_{(g)} \rightleftharpoons 2H_{2(g)} + S_{2(g)}$,the equilibrium mixture is given. If $1 \ mol$ of $H_2S$,$0.2 \ mol$ of $H_2$,and $0.8 \ mol$ of $S_2$ are taken in a $2 \ L$ vessel,find the value of $K_c$.

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$4.5$ moles each of hydrogen and iodine are heated in a sealed $10 \ L$ vessel. At equilibrium,$3$ moles of $HI$ are found. The equilibrium constant for ${H_2}_{(g)} + {I_2}_{(g)} \rightleftharpoons 2HI_{(g)}$ is

(i) $H_3PO_{4\text{(aq)}} \rightleftharpoons H^+{_{\text{(aq)}}} + H_2PO_4^-{_{\text{(aq)}}}$
(ii) $H_2PO_4^-{_{\text{(aq)}}} \rightleftharpoons H^+{_{\text{(aq)}}} + HPO_4^{2-}{_{\text{(aq)}}}$
(iii) $HPO_4^{2-}{_{\text{(aq)}}} \rightleftharpoons H^+{_{\text{(aq)}}} + PO_4^{3-}{_{\text{(aq)}}}$
The equilibrium constants for the above reactions at a certain temperature are $K_1$,$K_2$,and $K_3$ respectively. The equilibrium constant for the reaction $H_3PO_{4\text{(aq)}} \rightleftharpoons 3H^{+}{_{\text{(aq)}}} + PO_4^{3-}{_{\text{(aq)}}}$
$K = K_1 \times K_2 \times K_3$ is

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