Consider the following reactions. Total number of electrons in the $\pi$ bonds and lone pair of electrons in the product is:

  • A
    $12$
  • B
    $16$
  • C
    $14$
  • D
    $18$

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An organic compound having the molecular formula $C_8H_{10}O$ on being heated with $I_2$ and dilute $NaOH$ gives a yellow precipitate. The expected compound is

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The reaction sequence is as follows:
$Cyclopentanecarboxamide$ $\xrightarrow{P_2O_5, \Delta} W$ $\xrightarrow{CH_3MgBr, H_3^+O} X$ $\xrightarrow{Ca(OH)_2, I_2 (\text{yellow ppt.})} Y$ $\xrightarrow{\Delta} Z$
$Z$ is:

Treatment of propionaldehyde with dil. $NaOH$ gives:

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Amongst the following compounds, the one that will not respond to Cannizzaro reaction upon treatment with alkali is

Match List-$I$ with List-$II$ and then select the correct answer from the codes given below.
List-$I$List-$II$
$A$. $C_6H_6 + CO + HCl \xrightarrow{AlCl_3} C_6H_5CHO$$a$. Gattermann-Koch reaction
$B$. $C_6H_5CH_3 \xrightarrow{CrO_2Cl_2} C_6H_5CHO$$b$. Etard reaction
$C$. $C_6H_5CH_2Br + CH_3Br \xrightarrow{Na/ether} C_6H_5CH_2CH_3$$c$. Wurtz-Fittig reaction
$D$. $C_6H_6 + (CH_3)_2C = CH_2 \xrightarrow{H_2SO_4} C_6H_5C(CH_3)_3$$d$. Friedel-Crafts alkylation

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