Dalton's law of partial pressure is not applicable for which of the following mixtures?

At identical temperature and pressure, the rate of diffusion of hydrogen gas is $3\sqrt{3}$ times that of a hydrocarbon having molecular formula $C_n H_{2n-2}$. What is the value of '$n$'?

The units of surface tension and viscosity of liquids respectively are

$A$ gaseous mixture of $3$ gases $A$, $B$ and $C$ has a pressure of $10 \,atm$. The total number of moles is $10$. If the partial pressures of gases $A$ and $B$ are $3 \,atm$ and $1 \,atm$ respectively, and the molar mass of gas $C$ is $2 \,g/mol$, calculate the weight of $C$ in the mixture. (in $\,g$)

Pressure-volume $(pV)$ work done by an ideal gaseous system at constant volume is (where $E$ is internal energy of the system):

In which of the following gas mixtures does Dalton's Law of Partial Pressure not apply? Why?
$(i)$ $CO_2 + O_2 + N_2$
$(ii)$ $CO + O_2$
$(iii)$ $NH_3 + HCl$
$(iv)$ $HCl + O_2$