Describe the change in hybridisation (if any) of the $Al$ atom in the following reaction.
$AlCl_{3} + Cl^{-} \longrightarrow AlCl_{4}^{-}$

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) In $AlCl_{3}$,the aluminium atom is in the $sp^{2}$ hybridised state,resulting in a trigonal planar geometry.
When $AlCl_{3}$ reacts with $Cl^{-}$ to form $AlCl_{4}^{-}$,the lone pair from the chloride ion is donated into the empty $3p_{z}$ orbital of the aluminium atom.
Consequently,the hybridisation of the $Al$ atom changes from $sp^{2}$ to $sp^{3}$,and the geometry changes from trigonal planar to tetrahedral.

Explore More

Similar Questions

Suggest reasons why the $B-F$ bond lengths in $BF_{3}$ $(130 \ pm)$ and $BF_{4}^{-}$ $(143 \ pm)$ differ.

The number of molecules/ions from the following in which the central atom is involved in $sp^3$ hybridization is: $NO_3^{-}, BCl_3, ClO_2^{-}, ClO_3$

In which of the following molecules/ions $BF_3$,$NO_2^-$,$NH_2^-$ and $H_2O$,the central atom is $sp^2$ hybridised?

Which of the following compounds has $sp^2$ hybridization?

Identify the correct match:
Column $I$ (Molecule/ion) Column $II$ (Hybridisation)
$A$. $H_3O^{+}$ $P$. $sp$
$B$. $NH_2^{-}$ $Q$. $sp^2$
$C$. $NO_3^{-}$ $R$. $sp^3$
$D$. $ClF_3$ $S$. $sp^3d$

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo