Describe the hybridization in $PCl_{5}$. Why are the axial bonds longer as compared to equatorial bonds?

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) $1$. Hybridization: In $PCl_{5}$,the central phosphorus atom $(P)$ undergoes $sp^{3}d$ hybridization. In the excited state,one $3s$ electron is promoted to the $3d$ orbital,resulting in five half-filled orbitals $(3s, 3p_{x}, 3p_{y}, 3p_{z}, 3d_{z^{2}})$ which hybridize to form five equivalent $sp^{3}d$ hybrid orbitals.
$2$. Geometry: These five $sp^{3}d$ hybrid orbitals are directed towards the corners of a trigonal bipyramid,forming five $P-Cl$ $\sigma$-bonds.
$3$. Bond Lengths: The axial $P-Cl$ bonds are longer than the equatorial $P-Cl$ bonds because the three equatorial $Cl$ atoms exert greater repulsive forces on the two axial $Cl$ atoms. To minimize this repulsion,the axial bonds are pushed slightly away,resulting in a longer bond length compared to the equatorial bonds.

Explore More

Similar Questions

What is the $C - C$ bond length in molecules with $sp^2$ hybridization (in $\mathring{A}$)?

The $H-C-H$ bond angle in $CH_4$ molecule is

The hybridisations of $N$,$C$ and $O$ shown in the following compound are:

The hybridisation of the central atom $I$ in $IF_7$ is:

Describe the change in hybridization (if any) of the $Al$ atom in the following reaction:
$AlCl_3 + Cl^{-} \to AlCl_4^-$

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo