Diagonal relationship is shown by

The number of the following pairs of elements which exhibit a diagonal relationship is:
$1. B \text{ and } Si$
$2. Be \text{ and } Al$
$3. Li \text{ and } Mg$
$4. Al \text{ and } S$

Match the following properties in Column-$I$ with their correct trends in Column-$II$:

Column-$I$	Column-$II$
$A$. Ionisation potential	$P$. $O < F < N$
$B$. Electronegativity	$Q$. $N < O < F$
$C$. $Z_{eff}$	$R$. $O < N < F$
$D$. Electron affinity	$S$. $N < C < O$

The ionisation enthalpies of elements of the second period are given below: Ionisation enthalpy / $kcal \, mol^{-1}$: $520, 899, 801, 1086, 1402, 1314, 1681, 2080$. Match the correct enthalpy with the elements and complete the graph given in Fig. Also,write the symbols of the elements with their atomic numbers.

In which of the following options does the order of arrangement not agree with the variation of property indicated against it?

Match List – $I$ with List – $II$

List – $I$ (Element, Atomic number)	List – $II$ (Position in periodic table)
$(a)$ $Ra$ – $88$	$(i)$ $4^{th}$ period, $13^{th}$ group
$(b)$ $Ga$ – $31$	(ii) $6^{th}$ period, $6^{th}$ group
$(c)$ $W$ – $74$	(iii) $5^{th}$ period, $10^{th}$ group
$(d)$ $Pd$ – $46$	(iv) $7^{th}$ period, $2^{nd}$ group