Efficiency of the following cell is $84\%$. $A_{(s)} + B^{2+}(aq.) \rightleftharpoons A^{2+}(aq.) + B_{(s)}$; $\Delta H^o = -285 \ kJ$. Then the standard $EMF$ of the cell will be ........... $V$.

  • A
    $1.20$
  • B
    $2.40$
  • C
    $1.10$
  • D
    $1.24$

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The standard reduction potentials of $2H^{+}/H_2$,$Cu^{2+}/Cu$,$Zn^{2+}/Zn$,and $NO_3^{-}, H^{+}/NO$ are $0.0 \ V$,$0.34 \ V$,$-0.76 \ V$,and $0.97 \ V$ respectively. Observe the following reactions:
$I$. $Zn + HCl \rightarrow$
$II$. $Cu + HCl \rightarrow$
$III$. $Cu + HNO_3 \rightarrow$
Which reactions do not liberate $H_{2(g)}$?

Given ${E^o}_{Hg^{2+}|Hg_2^{2+}} = 0.9 \ V$ and ${E^o}_{Hg_2^{2+}|Hg} = 0.8 \ V$. Calculate the value of ${\Delta _r}{G^o}$ at $25 \ ^oC$ in $kJ/mol$ for the reaction: $Hg_2^{2+} \to Hg^{2+} + Hg_{(l)}$

The molar conductivity of $0.025 \ mol \ L^{-1}$ methanoic acid is $46.1 \ S \ cm^2 \ mol^{-1}$. Calculate its degree of dissociation and dissociation constant. Given $\lambda^o(H^{+}) = 349.6 \ S \ cm^2 \ mol^{-1}$ and $\lambda^o(HCOO^{-}) = 54.6 \ S \ cm^2 \ mol^{-1}$.

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For the reaction $4B_{(s)} + 3O_{2(g)} \rightarrow 2B_2O_{3(g)}$,the standard cell potential is $E^o_{cell} = 1.433 \ V$. Calculate the molar entropy $(S_m^o)$ of oxygen gas in $J/K \ mol$.
Given:
$(\Delta_fH^o)_{B_2O_3(g)} = -840 \ kJ/mol$
$(S_m^o)_{B_2O_3(g)} = 280 \ J/K \ mol$
$(S_m^o)_{B(s)} = 10 \ J/K \ mol$
Assume $\Delta_rG^o = -nFE^o_{cell}$ and $\Delta_rG^o = \Delta_rH^o - T\Delta_rS^o$ at $T = 298 \ K$.

In a fuel cell,methanol is used as fuel and oxygen gas is used as an oxidizer. The reaction is
$CH_3OH_{(l)} + \frac{3}{2} O_{2(g)} \rightarrow CO_{2(g)} + 2H_2O_{(l)}$
At $298 \ K$,standard Gibbs energies of formation for $CH_3OH_{(l)}$,$H_2O_{(l)}$,and $CO_{2(g)}$ are $-166.2$,$-237.2$,and $-394.4 \ kJ \ mol^{-1}$ respectively. If the standard enthalpy of combustion of methanol is $-726 \ kJ \ mol^{-1}$,the efficiency of the fuel cell will be .......... $\%$.

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