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On which principle does the zone refining method work?

Blister copper is

Which one of the following is most likely a mismatch?

Which process of purification is represented by the following scheme?
$\text{Ti}_{\text{impure}} + 2I_2$ $\xrightarrow{250^{\circ}C} TiI_4$ $\xrightarrow{1400^{\circ}C} \text{Ti}_{\text{pure}} + 2I_2$

Which method is used to obtain ultra-pure copper?

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