Explain the average rate of reaction for a hypothetical $R \longrightarrow P$ reaction.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
Consider a hypothetical reaction where the volume of the system remains constant.
Reaction: $R \longrightarrow P$
Suppose at time $t_{1}$,the concentration of reactant $R$ is $[R]_{1}$.
Suppose at time $t_{2}$,the concentration of reactant $R$ is $[R]_{2}$.
The change in time is $\Delta t = t_{2} - t_{1}$.
The change in concentration of the reactant is $\Delta[R] = [R]_{2} - [R]_{1}$.
The rate of decrease in the concentration of reactant $R$ is given by:
Average Rate $= -\frac{\Delta[R]}{\Delta t} = -\frac{[R]_{2} - [R]_{1}}{t_{2} - t_{1}} \dots (i)$
Similarly,if at time $t_{1}$ the concentration of product $P$ is $[P]_{1}$ and at time $t_{2}$ it is $[P]_{2}$,the increase in concentration of the product is $\Delta[P] = [P]_{2} - [P]_{1}$.
The rate of formation of product $P$ is given by:
Average Rate $= +\frac{\Delta[P]}{\Delta t} = +\frac{[P]_{2} - [P]_{1}}{t_{2} - t_{1}} \dots (ii)$
Equating $(i)$ and $(ii)$,the average rate of reaction is:
Average Rate $= -\frac{\Delta[R]}{\Delta t} = +\frac{\Delta[P]}{\Delta t}$

Explore More

Similar Questions

$A \rightarrow P$ is a first-order reaction. The following graph is obtained for this reaction ($x$-axis $=$ time,$y$-axis $=$ concentration of $A$). The instantaneous rate of the reaction at point $C$ is:

For the reaction $6H^+ + BrO_3^- + 5Br^- \to 3Br_2 + 3H_2O$,which of the following relations is correct for the rate of consumption and formation of products?

Consider a gas phase reaction which occurs in a closed vessel: $2 \ A \rightarrow 4 \ B + C$. The concentration of $B$ is found to be increased by $5 \times 10^{-3} \ mol \ L^{-1}$ in $10 \ s$. The rate of disappearance of $A$ (in $mol \ L^{-1} \ s^{-1}$) is:

For the reaction $2SO_2 + O_2 \to 2SO_3$,the rate of disappearance of $O_2$ is $2.0 \times 10^{-4} \ mol \ L^{-1}s^{-1}$. The rate of appearance of $SO_3$ is:

Which of the following is the fastest reaction?

Difficult
View Solution

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo