Explain how the energy of an orbital and the extent of shielding in the same shell depend on the shape of the orbitals.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) Both the attractive and repulsive interactions depend upon the shell and the shape of the orbital in which the electron is present. The reasons are as follows:
$(i)$ The $s$-orbital shields the outer electrons from the nucleus more effectively compared to electrons present in the $p$-orbital.
$(ii)$ Due to the spherical shape of the $s$-orbital,the $s$-orbital electron spends more time close to the nucleus in comparison to the $p$-orbital electron,which in turn spends more time near the nucleus compared to the $d$-orbital electron.
$(iii)$ Effective nuclear charge $(Z_{eff})$: As the azimuthal quantum number $(l)$ increases,the $Z_{eff}$ experienced by the electron decreases. Consequently,the $s$-orbital electron is more tightly bound to the nucleus than the $p$-orbital electron,which is more tightly bound than the $d$-orbital electron.
Result: The energy order of orbitals in the same shell is $s < p < d < f$.

Explore More

Similar Questions

The orbital angular momentum of a $3p$ electron is

The spin angular momentum for an electron is given by .......

Explain the differences between the $1s$ and $2s$ orbitals based on their probability density plots and radial distribution.

Difficult
View Solution

Which of the following is violating Hund's rule?

In the case of a hydrogen atom,which of the following transitions does not involve the absorption or emission of energy?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo