Explain the nature of the $C-X$ bond in alkyl halides.

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Halogen atoms are more electronegative than carbon; therefore,the carbon-halogen bond of an alkyl halide is polarized. The carbon atom bears a partial positive charge $(\delta+)$ whereas the halogen atom bears a partial negative charge $(\delta-)$. The bond is represented as $C^{\delta+}-X^{\delta-}$.
As we go down the group in the periodic table,the size of the halogen atom increases. The fluorine atom is the smallest and the iodine atom is the largest. Consequently,the carbon-halogen bond length increases from $C-F$ to $C-I$.
Carbon-Halogen $(C-X)$ Bond Lengths,Bond Enthalpies,and Dipole Moments:
Bond Bond length $/ pm$ $C-X$ Bond enthalpies $/ (kJ \ mol^{-1})$ Dipole moment $/$ Debye
$CH_3F$ $139$ $452$ $1.847$
$CH_3Cl$ $178$ $351$ $1.860$
$CH_3Br$ $193$ $293$ $1.830$
$CH_3I$ $214$ $234$ $1.636$

Order of dipole moment: $CH_3Cl$ > $CH_3F$ > $CH_3Br$ > $CH_3I$
Order of bond enthalpies: $CH_3F$ > $CH_3Cl$ > $CH_3Br$ > $CH_3I$

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Similar Questions

Column-$(I)$ contains the formula of an alkyl halide and Column-$(II)$ contains its type. Match Column-$(I)$ with Column-$(II)$.
Column-$(I)$ Column-$(II)$
$(A)$ $CH_3CH_2X$ $(1)$ $4^{\circ}$ halide
$(B)$ $R'CH_2X$ $(2)$ $3^{\circ}$ halide
$(C)$ $R'R''CHX$ $(3)$ $2^{\circ}$ halide
$(D)$ $R'R''CR'''X$ $(4)$ $1^{\circ}$ halide

Which among the following examples of halogen derivatives does $NOT$ correctly match with its type of compound?

Which of the following is an allylic halide?

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Which of the following compounds is not an allylic chloride?

Match the type of hybridization of the carbon atom attached to the halogen in Column-$I$ with the hybridization type in Column-$II$.
Column-$I$ (Structure) Column-$II$ (Hybridization)
$A$. $CH_3CH_2Cl$ $i$. $sp$
$B$. $CH_2=CHCl$ $ii$. $sp^2$
$C$. $CH_2=CH-CH_2Cl$ $iii$. $sp^3$
$D$. Chlorobenzene $iv$. $sp^3d$

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