| Bond | Bond length $/ pm$ | $C-X$ Bond enthalpies $/ (kJ \ mol^{-1})$ | Dipole moment $/$ Debye |
| $CH_3F$ | $139$ | $452$ | $1.847$ |
| $CH_3Cl$ | $178$ | $351$ | $1.860$ |
| $CH_3Br$ | $193$ | $293$ | $1.830$ |
| $CH_3I$ | $214$ | $234$ | $1.636$ |
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| Column-$(I)$ | Column-$(II)$ |
| $(A)$ $CH_3CH_2X$ | $(1)$ $4^{\circ}$ halide |
| $(B)$ $R'CH_2X$ | $(2)$ $3^{\circ}$ halide |
| $(C)$ $R'R''CHX$ | $(3)$ $2^{\circ}$ halide |
| $(D)$ $R'R''CR'''X$ | $(4)$ $1^{\circ}$ halide |
| Column-$I$ (Structure) | Column-$II$ (Hybridization) |
| $A$. $CH_3CH_2Cl$ | $i$. $sp$ |
| $B$. $CH_2=CHCl$ | $ii$. $sp^2$ |
| $C$. $CH_2=CH-CH_2Cl$ | $iii$. $sp^3$ |
| $D$. Chlorobenzene | $iv$. $sp^3d$ |
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