Ferric ion forms a Prussian blue precipitate due to the formation of

  • A
    $K_4[Fe(CN)_6]$
  • B
    $K_3[Fe(CN)_6]$
  • C
    $Fe(CNS)_3$
  • D
    $Fe_4[Fe(CN)_6]_3$

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The reagent used for the detection of $Ni^{2+}$ is $A$. $x$ moles of $A$ react with $Ni^{2+}$ to form a complex of $C$ color. $A$,$x$,and $C$ are respectively:

If a didentate ligand ethane-$1, 2$-diamine is progressively added in the molar ratio $en : Ni :: 1: 1, 2: 1, 3: 1$ to $[Ni(H_2O)_6]^{2+}$ aqueous solution,the following coordination entities are formed:
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Assign $A, B, C, D$ from the given type of reaction.
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Sodium nitroprusside when added to an alkaline solution of sulphide ions produces a:

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