Find the solubility product $(K_{sp})$ of a saturated solution of $Ag_2CrO_4$ in water at $298 \ K$,if the $emf$ of the cell $Ag | Ag^{+} (\text{satd. } Ag_2CrO_4 \text{ solution}) || Ag^{+} (0.1 \ M) | Ag$ is $0.591 \ V$ at $298 \ K$.

  • A
    $5 \times 10^{-12} \ M^3$
  • B
    $7.2 \times 10^{-12} \ M^3$
  • C
    $4.3 \times 10^{-12} \ M^3$
  • D
    $5 \times 10^{-34} \ M^3$

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The conductivity of $0.001028 \, mol \, L^{-1}$ acetic acid is $4.95 \times 10^{-5} \, S \, cm^{-1}$. Calculate its dissociation constant if $\Lambda_m^\circ$ for acetic acid is $390.5 \, S \, cm^2 \, mol^{-1}$.

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$100 \text{ mL}$ of $0.2 \text{ M}$ acetic acid is completely neutralized using a standard solution of $NaOH$. The volume of ethane obtained at $STP$ after complete electrolysis of the resulting solution is: (in $\text{ L}$)

Which of the following is not correct?

Why is electrochemistry important for the invention of the latest technology?

Consider the following electrochemical cell at standard condition: $Au_{(s)} | QH_2, Q | NH_4X(0.01 \ M) || Ag^{+}(1 \ M) | Ag_{(s)}$. Given $E_{\text{cell}} = +0.4 \ V$. The couple $QH_2 / Q$ represents the quinhydrone electrode,and the half-cell reaction is given as: $Q + 2e^- + 2H^+ \rightarrow QH_2$ with $E^o_{Q/QH_2} = +0.7 \ V$. Given: $E^o_{Ag^+/Ag} = +0.8 \ V$ and $\frac{2.303 \ RT}{F} = 0.06 \ V$. The $pK_b$ value of the ammonium halide salt $(NH_4X)$ used here is $.........$ (nearest integer).

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