The following is a confirmatory test for aromatic primary amines. Identify reagent $(A)$ and $(B)$.

  • A
    $A = NaNO_2 + HCl, 0-5^{\circ}C$; $B = \text{Phenol}$
  • B
    $A = NaNO_2 + HCl, 0-5^{\circ}C$; $B = \text{Aniline}$
  • C
    $A = NaNO_2 + HCl, 0-5^{\circ}C$; $B = \alpha\text{-Naphthol}$
  • D
    $A = NaNO_2 + HCl, 0-5^{\circ}C$; $B = \beta\text{-Naphthol}$

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Methyl isocyanide on hydrolysis gives

Match List $I$ with List $II$:
List $I$ (Amines)List $II$ $(pK_{b})$
$A$. Aniline$I$. $3.25$
$B$. Ethanamine$II$. $3.00$
$C$. $N$-Ethylethanamine$III$. $9.38$
$D$. $N,N$-Diethylethanamine$IV$. $3.29$

Choose the correct answer from the options given below:

Select the compound which on treatment with nitrous acid liberates nitrogen.

Consider the following reaction sequence and identify the correct option:

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Which one of the following compounds gives carboxylic acid with $HNO_2$?

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