For the reaction,$NO_{2(g)} + CO_{(g)} \longrightarrow NO_{(g)} + CO_{2(g)}$,the rate of reaction is proportional to the square of $[NO_2]$ and independent of $[CO]$. What is the rate law equation?
- A$r = k \frac{[NO_2]^{1/2}}{[CO]}$
- B$r = k [NO_2]^2 [CO]^0$
- C$r = \frac{1}{2} k [NO_2] [CO]$
- D$r = k [NO_2]^2 [CO]$
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View SolutionFor the gaseous reaction,$N_2O_5 \rightarrow 2NO_2 + \frac{1}{2}O_2$,the rate can be expressed as:
$-\frac{d[N_2O_5]}{dt} = K_1[N_2O_5]$
$+\frac{d[NO_2]}{dt} = K_2[N_2O_5]$
$+\frac{d[O_2]}{dt} = K_3[N_2O_5]$
The correct relation between $K_1, K_2$ and $K_3$ is:
$-\frac{d[N_2O_5]}{dt} = K_1[N_2O_5]$
$+\frac{d[NO_2]}{dt} = K_2[N_2O_5]$
$+\frac{d[O_2]}{dt} = K_3[N_2O_5]$
The correct relation between $K_1, K_2$ and $K_3$ is:
The following results have been obtained during the kinetic studies of the reaction: $2 \ NO + 2 \ H_2 \longrightarrow N_2 + 2 \ H_2O$
Expt $\frac{-d[NO]}{dt} \ (mol \ L^{-1} \ s^{-1})$ $[NO] \ (mol \ L^{-1})$ $[H_2] \ (mol \ L^{-1})$ $1$ $4.8 \times 10^{-5}$ $1 \times 10^{-2}$ $1 \times 10^{-3}$ $2$ $43.2 \times 10^{-5}$ $3 \times 10^{-2}$ $1 \times 10^{-3}$ $3$ $86.4 \times 10^{-5}$ $3 \times 10^{-2}$ $2 \times 10^{-3}$
| Expt | $\frac{-d[NO]}{dt} \ (mol \ L^{-1} \ s^{-1})$ | $[NO] \ (mol \ L^{-1})$ | $[H_2] \ (mol \ L^{-1})$ |
| $1$ | $4.8 \times 10^{-5}$ | $1 \times 10^{-2}$ | $1 \times 10^{-3}$ |
| $2$ | $43.2 \times 10^{-5}$ | $3 \times 10^{-2}$ | $1 \times 10^{-3}$ |
| $3$ | $86.4 \times 10^{-5}$ | $3 \times 10^{-2}$ | $2 \times 10^{-3}$ |
Certain bimolecular reactions which follow the first order kinetics are called
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