Formation of $NO_{2(g)}$ from $N_{2(g)}$ and $O_{2(g)}$ is an endothermic process. Which of the following is true for this reaction?

  • A
    $\Delta H = 0$
  • B
    $\Delta H < 0$
  • C
    $\Delta H = \Delta U$
  • D
    $\Delta H > 0$

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If the bond dissociation energies of $XY$,$X_2$,and $Y_2$ (all diatomic molecules) are in the ratio of $1 : 1 : 0.5$ and $\Delta_f H$ for the formation of $XY$ is $-200 \ kJ \ mol^{-1}$,the bond dissociation energy of $X_2$ will be in $kJ \ mol^{-1}$:

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