From the following bond energies:

$H-H$ bond energy	$431.37 \text{ kJ mol}^{-1}$
$C=C$ bond energy	$606.10 \text{ kJ mol}^{-1}$
$C-C$ bond energy	$336.49 \text{ kJ mol}^{-1}$
$C-H$ bond energy	$410.50 \text{ kJ mol}^{-1}$

Enthalpy for the reaction $CH_2=CH_2 + H-H \to CH_3-CH_3$ will be .............. $\text{kJ mol}^{-1}$

Standard molar enthalpy of formation of $CO_2$ is equal to

Fill in the blanks:
$(i)$ The enthalpy change that occurs when one mole of a compound is formed from its constituent elements in their standard states is called the ...... of that compound.
$(ii)$ The total heat change in a chemical reaction is equal to the algebraic sum of the heat changes of the individual steps of the reaction. This law was given by ............. .
$(iii)$ $A$ process during which there is no exchange of heat between the system and the surroundings is called an ................ process.
$(iv)$ The standard enthalpy value of any element in its standard state is considered to be ...... .

Calculate the enthalpy of formation of sucrose $(C_{12}H_{22}O_{11})$ in $kJ \, mol^{-1}$ using the following data:
$(i) \, C_{12}H_{22}O_{11} + 12O_2 \to 12CO_2 + 11H_2O, \, \Delta H = -5200.7 \, kJ \, mol^{-1}$
$(ii) \, C + O_2 \to CO_2, \, \Delta H = -394.5 \, kJ \, mol^{-1}$
$(iii) \, H_2 + \frac{1}{2}O_2 \to H_2O, \, \Delta H = -285.8 \, kJ \, mol^{-1}$

Fill in the blanks:
$(i)$ The enthalpy change that occurs when one mole of a compound is formed from its constituent elements in their standard states is called the ....... of that compound.
$(ii)$ The total heat change in a chemical reaction is equal to the algebraic sum of the heat changes of the individual steps of the reaction. This law was given by .......... .
$(iii)$ $A$ process during which there is no exchange of heat between the system and the surroundings is called an ........... process.

Calculate the $N-N$ bond energy in $N_2H_4$ from the given bond enthalpy data.
$\varepsilon_{N-H} = 393 \ kJ/mol$
$\varepsilon_{H-H} = 436 \ kJ/mol$
$\Delta H_{vap}[N_2H_{4(l)}] = 18 \ kJ/mol$
$N_2H_{4(l)} + H_{2(g)} \to 2NH_{3(g)} : \Delta H = -142 \ kJ/mol$
....... $kJ/mol$