Give equations of the following reactions:
$(i)$ Oxidation of propan$-1-$ol with alkaline $KMnO_4$ solution.
$(ii)$ Bromine in $CS_2$ with phenol.
$(iii)$ Dilute $HNO_3$ with phenol.
$(iv)$ Treating phenol with chloroform in presence of aqueous $NaOH$.

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(N/A) $(i)$ $CH_3CH_2CH_2OH \xrightarrow{\text{alk. } KMnO_4} CH_3CH_2COOH$ (Propanoic acid)
$(ii)$ Phenol reacts with $Br_2$ in $CS_2$ at $273 \ K$ to give a mixture of $o$-bromophenol (minor) and $p$-bromophenol (major).
$(iii)$ Phenol reacts with dilute $HNO_3$ at low temperature to give a mixture of $o$-nitrophenol and $p$-nitrophenol.
$(iv)$ Phenol reacts with $CHCl_3$ in the presence of aqueous $NaOH$ (Reimer-Tiemann reaction) to form salicylaldehyde.

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Match the following column:
Column-$I$ (Reaction) Column-$II$ (Electrophile)
$A$. $C_6H_6 + CH_3Cl \xrightarrow{AlCl_3} C_6H_5CH_3$ $P$. $CO_2$
$B$. $C_6H_5OH + CO_2 \xrightarrow[H^+]{NaOH} \text{Salicylic acid}$ $Q$. $:CCl_2$
$C$. $C_6H_5OH + CHCl_3 \xrightarrow{KOH} \text{Salicylaldehyde}$ $R$. $\stackrel{+}{C}H_3$
$D$. $C_6H_6 + SO_3 \xrightarrow{H_2SO_4} C_6H_5SO_3H$ $S$. $\stackrel{+}{S}O_3H$
$T$. $SO_3$

List-$I$ contains reactions and List-$II$ contains major products. Match each reaction in List-$I$ with one or more products in List-$II$ and choose the correct option.

Match each of the compounds given in Column $I$ with the reaction$(s)$ that they can undergo,given in Column $II$.
| Column $I$ | Column $II$ |
| :--- | :--- |
| $(A)$ $3-$bromobenzofuran derivative | $(p)$ Nucleophilic substitution |
| $(B)$ Benzyl alcohol | $(q)$ Elimination |
| $(C)$ Salicylaldehyde | $(r)$ Nucleophilic addition |
| $(D)$ $1-$bromo$-2-$nitrobenzene | $(s)$ Esterification with acetic anhydride |
| | $(t)$ Dehydrogenation |

$1.12 \, mL$ of a gas is produced at $STP$ by the action of $4.12 \, mg$ of alcohol with methyl magnesium iodide. The molecular mass of the alcohol is:

Identify $A$ in the following chemical reaction:

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