Given below are two statements.
Statement $I$: In $CuSO_{4} \cdot 5H_{2}O$,$Cu-O$ bonds are present.
Statement $II$: In $CuSO_{4} \cdot 5H_{2}O$,ligands coordinating with $Cu(II)$ ion are $O$- and $S$-based ligands.
In the light of the above statements,choose the correct answer from the options given below.

  • A
    Both Statement $I$ and Statement $II$ are correct
  • B
    Both Statement $I$ and Statement $II$ are incorrect
  • C
    Statement $I$ is correct but Statement $II$ is incorrect
  • D
    Statement $I$ is incorrect but Statement $II$ is correct

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Which of the given statements is incorrect?

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$A$ mixture $X$ containing $0.02 \, mol$ of $[Co(NH_3)_5SO_4]Br$ and $0.02 \, mol$ of $[Co(NH_3)_5Br]SO_4$ is dissolved in water to make a $2 \, L$ solution.
$1 \, L \, of \, X + \text{Excess of } AgNO_3 \rightarrow Y \, mol \, of \, ppt.$
$1 \, L \, of \, X + \text{Excess of } BaCl_2 \rightarrow Z \, mol \, of \, ppt.$
Then $Y$ and $Z$ are respectively ...............

The ammonia prepared by treating ammonium sulphate with calcium hydroxide is completely used by $NiCl_2 \cdot 6H_2O$ to form a stable coordination compound. Assume that both the reactions are $100 \%$ complete. If $1584 \ g$ of ammonium sulphate and $952 \ g$ of $NiCl_2 \cdot 6H_2O$ are used in the preparation,the combined weight (in grams) of gypsum and the nickel-ammonia coordination compound thus produced is $\qquad$ (Atomic weights in $g \ mol^{-1}: H=1, N=14, O=16, S=32, Cl=35.5, Ca=40, Ni=59$)

The number of ions present in $2 \ L$ of a solution of $1.6 \ M \ K_4[Fe(CN)_6]$ is:

$0.001 \ mol$ of $Co(NH_3)_5(NO_3)(SO_4)$ was passed through a cation exchanger. The acid coming out of it required $20 \ mL$ of $0.1 \ M$ $NaOH$ for neutralization. Hence,the complex is:

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