Given below are two statements:
Statement $I$: For an ideal gas, heat capacity at constant volume is always greater than the heat capacity at constant pressure.
Statement $II$: In a constant volume process, no work is produced and all the heat withdrawn goes into the chaotic motion and is reflected by a temperature increase of the ideal gas.

The enthalpies of combustion of $S_{(s)}$ and $H_{2(g)}$ are $-300 \ kcal \ mol^{-1}$ and $-290 \ kcal \ mol^{-1}$ respectively. Given the following reactions:
$SO_{3(g)} + H_2O_{(l)} \rightarrow H_2SO_{4(l)}$; $\Delta H = -130 \ kcal \ mol^{-1}$
$SO_{2(g)} + 1/2 O_{2(g)} \rightarrow SO_{3(g)}$; $\Delta H = -100 \ kcal \ mol^{-1}$
$S_{(s)} + O_{2(g)} \rightarrow SO_{2(g)}$; $\Delta H = -300 \ kcal \ mol^{-1}$
$H_{2(g)} + 1/2 O_{2(g)} \rightarrow H_2O_{(l)}$; $\Delta H = -290 \ kcal \ mol^{-1}$
The enthalpy of formation of $H_2SO_{4(l)}$ is:

$5 \, mol$ of an ideal gas at $100 \, K$ are allowed to undergo reversible compression till its temperature becomes $200 \, K$. If $C_v = 28 \, J \, K^{-1} \, mol^{-1}$,calculate $\Delta U$ and $\Delta pV$ for this process. $(R = 8.0 \, J \, K^{-1} \, mol^{-1})$

One mole of a monatomic ideal gas undergoes four thermodynamic processes as shown schematically in the $PV$-diagram below. Among these four processes,one is isobaric,one is isochoric,one is isothermal and one is adiabatic. Match the processes mentioned in List-$I$ with the corresponding statements in List-$II$.

List-$I$	List-$II$
$P$. In process $I$	$1$. Work done by the gas is zero
$Q$. In process $II$	$2$. Temperature of the gas remains unchanged
$R$. In process $III$	$3$. No heat is exchanged between the gas and its surroundings
$S$. In process $IV$	$4$. Work done by the gas is $6 P_0 V_0$

Assuming the water vapour to be a perfect gas,calculate the internal energy change when $1 \ mol$ of water at $100^{\circ} C$ and $1 \ bar$ pressure is converted to ice at $0^{\circ} C$. Given the enthalpy of fusion of ice is $6.00 \ kJ \ mol^{-1}$ and heat capacity of water is $4.2 \ J \ g^{-1} {\circ} C^{-1}$.

For the following reaction occurring in automobiles,the values of $\Delta H, \Delta S, \text{and } \Delta G$ are respectively:
$2C_8H_{18(g)} + 25O_2(g) \rightarrow 16CO_2(g) + 18H_2O(g)$