Given below are two statements:
Statement-$I$ : Oxidation of $p$-nitrotoluene with acidic $KMnO_4$ gives an acid that is stronger than benzoic acid.
Statement-$II$ : Reduction of $p$-nitrotoluene with $Sn/HCl$ followed by neutralization gives an amine that is more basic than aniline.
In light of the above statements, choose the most appropriate answer from the options given below.
Statement-$I$ : Oxidation of $p$-nitrotoluene with acidic $KMnO_4$ gives an acid that is stronger than benzoic acid.
Statement-$II$ : Reduction of $p$-nitrotoluene with $Sn/HCl$ followed by neutralization gives an amine that is more basic than aniline.
In light of the above statements, choose the most appropriate answer from the options given below.
- ABoth Statement-$I$ and Statement-$II$ are correct
- BBoth Statement-$I$ and Statement-$II$ are incorrect
- CStatement-$I$ is correct but Statement-$II$ is incorrect
- DStatement-$I$ is incorrect but Statement-$II$ is correct
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Similar Questions
Match each of the compounds in Column $I$ with its characteristic reaction$(s)$ in Column $II$.
Column $I$ Column $II$ $A$. $CH_3CH_2CH_2CN$ $p$. Reduction with $Pd-C/H_2$ $B$. $CH_3CH_2OCOCH_3$ $q$. Reduction with $SnCl_2/HCl$ $C$. $CH_3-CH=CH-CH_2OH$ $r$. Development of foul smell on treatment with chloroform and alcoholic $KOH$ $D$. $CH_3CH_2CH_2CH_2NH_2$ $s$. Reduction with diisobutylaluminium hydride $(DIBAL-H)$ $t$. Alkaline hydrolysis
| Column $I$ | Column $II$ |
|---|---|
| $A$. $CH_3CH_2CH_2CN$ | $p$. Reduction with $Pd-C/H_2$ |
| $B$. $CH_3CH_2OCOCH_3$ | $q$. Reduction with $SnCl_2/HCl$ |
| $C$. $CH_3-CH=CH-CH_2OH$ | $r$. Development of foul smell on treatment with chloroform and alcoholic $KOH$ |
| $D$. $CH_3CH_2CH_2CH_2NH_2$ | $s$. Reduction with diisobutylaluminium hydride $(DIBAL-H)$ |
| $t$. Alkaline hydrolysis |
Amongst the compounds given,the one that would form a brilliant colored dye on treatment with $NaNO_2$ in dil. $HCl$ followed by addition to an alkaline solution of $\beta$-naphthol is
DifficultIIT 2011
View SolutionAmong the compounds given below,the order of basicity is:
$(I)$ Piperidine
$(II)$ Pyridine
$(III)$ Morpholine
$(IV)$ Pyrrole
$(I)$ Piperidine
$(II)$ Pyridine
$(III)$ Morpholine
$(IV)$ Pyrrole
MediumKVPY 2009
View SolutionBenzyl isocyanide can be obtained from which of the following reactions? Choose the correct answer from the options given below:
$A$. Benzyl bromide + $AgCN$
$B$. Benzylamine + $CHCl_3$ + $Aq. NaOH$
$C$. Bromobenzene + $AgCN$
$D$. Aniline + $CHCl_3$ + $Aq. NaOH$
$E$. $2-$Phenylethyl bromide + $KCN$
$A$. Benzyl bromide + $AgCN$
$B$. Benzylamine + $CHCl_3$ + $Aq. NaOH$
$C$. Bromobenzene + $AgCN$
$D$. Aniline + $CHCl_3$ + $Aq. NaOH$
$E$. $2-$Phenylethyl bromide + $KCN$
Amine compounds exhibit ............ isomerism.
Medium
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