Given that $Ni^{2+}/Ni = -0.25 \ V$; $Cu^{2+}/Cu = 0.34 \ V$; $Ag^{+}/Ag = 0.80 \ V$; $Zn^{2+}/Zn = -0.76 \ V$. Which of the following reactions under standard conditions will not take place in the specified direction?
- A$Ni^{2+}_{(aq)} + Cu_{(s)} \to Ni_{(s)} + Cu^{2+}_{(aq)}$
- B$2Ag^{+}_{(aq)} + Cu_{(s)} \to 2Ag_{(s)} + Cu^{2+}_{(aq)}$
- C$Zn_{(s)} + Cu^{2+}_{(aq)} \to Zn^{2+}_{(aq)} + Cu_{(s)}$
- D$2H^{+}_{(aq)} + Zn_{(s)} \to H_{2(g)} + Zn^{2+}_{(aq)}$
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Similar Questions
The standard electrode potential $E^{\ominus}$ and its temperature coefficient $\left( \frac{dE^{\ominus}}{dT} \right)$ for a cell are $2 \ V$ and $-5 \times 10^{-4} \ V \ K^{-1}$ at $300 \ K$ respectively. The cell reaction is
$Zn_{(s)} + Cu^{2+}_{(aq)} \rightleftharpoons Zn^{2+}_{(aq)} + Cu_{(s)}$
Standard reaction enthalpy $\left( \Delta_r H^{\ominus} \right)$ is ....... $kJ$
$Zn_{(s)} + Cu^{2+}_{(aq)} \rightleftharpoons Zn^{2+}_{(aq)} + Cu_{(s)}$
Standard reaction enthalpy $\left( \Delta_r H^{\ominus} \right)$ is ....... $kJ$
DifficultJEE MAIN 2019
View SolutionWhich of the following statements is incorrect?
Easy
View SolutionCopper from copper sulphate solution can be displaced by .............. The standard reduction potentials of some electrodes are given below:
$E^o (Fe^{2+}, Fe) = -0.44 \ V$
$E^o (Zn^{2+}, Zn) = -0.76 \ V$
$E^o (Cu^{2+}, Cu) = +0.34 \ V$
$E^o (Cr^{2+}, Cr) = -0.74 \ V$
$E^o (H^{+}, 1/2H_2) = 0.00 \ V$
$E^o (Fe^{2+}, Fe) = -0.44 \ V$
$E^o (Zn^{2+}, Zn) = -0.76 \ V$
$E^o (Cu^{2+}, Cu) = +0.34 \ V$
$E^o (Cr^{2+}, Cr) = -0.74 \ V$
$E^o (H^{+}, 1/2H_2) = 0.00 \ V$
Medium
View SolutionCalculate the standard cell potentials of galvanic cells in which the following reactions take place:
$(i)$ $2Cr_{(s)} + 3Cd^{2+}_{(aq)} \rightarrow 2Cr^{3+}_{(aq)} + 3Cd_{(s)}$
$(ii)$ $Fe^{2+}_{(aq)} + Ag^{+}_{(aq)} \rightarrow Fe^{3+}_{(aq)} + Ag_{(s)}$
Calculate the $\Delta_r G^\Theta$ and equilibrium constant of the reactions.
$(i)$ $2Cr_{(s)} + 3Cd^{2+}_{(aq)} \rightarrow 2Cr^{3+}_{(aq)} + 3Cd_{(s)}$
$(ii)$ $Fe^{2+}_{(aq)} + Ag^{+}_{(aq)} \rightarrow Fe^{3+}_{(aq)} + Ag_{(s)}$
Calculate the $\Delta_r G^\Theta$ and equilibrium constant of the reactions.
Difficult
View SolutionGiven ${E^o}_{Hg^{2+}|Hg_2^{2+}} = 0.9 \ V$ and ${E^o}_{Hg_2^{2+}|Hg} = 0.8 \ V$. Calculate the value of ${\Delta _r}{G^o}$ at $25 \ ^oC$ in $kJ/mol$ for the reaction: $Hg_2^{2+} \to Hg^{2+} + Hg_{(l)}$
Medium
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