How would you explain the following observations?
$(i)$ $BeO$ is almost insoluble but $BeSO_4$ is soluble in water.
$(ii)$ $BaO$ is soluble but $BaSO_4$ is insoluble in water.
$(iii)$ $LiI$ is more soluble than $KI$ in ethanol.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) $(i)$ $BeO$ is almost insoluble in water because $Be^{2+}$ is a small cation with high charge density,leading to very high lattice energy that hydration energy cannot overcome. In $BeSO_4$,the large $SO_4^{2-}$ anion reduces the lattice energy,making it soluble.
$(ii)$ $BaO$ is soluble because $Ba^{2+}$ and $O^{2-}$ have a size mismatch,resulting in lower lattice energy that is easily overcome by hydration energy. In $BaSO_4$,both $Ba^{2+}$ and $SO_4^{2-}$ are large,leading to high lattice energy,making it insoluble.
$(iii)$ $LiI$ is more soluble than $KI$ in ethanol due to the higher polarising power of the small $Li^+$ ion,which imparts greater covalent character to $LiI$ compared to $KI$,facilitating its dissolution in organic solvents like ethanol.

Explore More

Similar Questions

$AgF, AgCl, NaCl, NaBr, NaI$ are colourless but $AgBr$ and $AgI$ are coloured because

Which of the following orders is incorrect?

Which of the following compounds exhibits covalent character?

Amongst $LiCl$,$BeCl_2$,$MgCl_2$,and $RbCl$,the compounds with the greatest and least ionic character,respectively,are:

Difficult
View Solution

The number of the following factors which affect the percent covalent character of the ionic bond is $............$.
$(a)$ Polarising power of cation
$(b)$ Extent of distortion of anion
$(c)$ Polarisability of the anion
$(d)$ Polarising power of anion

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo