Identify $Z$ in the following sequence of reactions.

  • A
    $2-$bromo$-4-$aminoethylbenzene
  • B
    $2-$bromo$-4-$carboxymethylbenzene
  • C
    $2-$bromo$-1,4-$dicarboxybenzene
  • D
    $2-$bromobenzoic acid

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The major product of the reaction is:

The product $(C)$ in the above reaction is:

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Assertion : Nitration of aniline can be conveniently done by protecting the amino group by acetylation.
Reason : Acetylation increases the electron density in the benzene ring.

What is the correct order of basicity for the given amines in a chlorobenzene medium?
$(A)$ $CH_3CH_2NH_2$
$(B)$ Cyclohexylamine
$(C)$ $N$-Methylpiperidine
$(D)$ Pyrrolidine

$A$ compound $X$ on treatment with $Br_2/NaOH$ provided $C_3H_9N$,which gives a positive carbylamine test. Compound $X$ is

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