Identify the major product formed in the following sequence of reactions:
Aniline $\xrightarrow{Br_2/H_2O}$ $2,4,6-$Tribromoaniline $\xrightarrow{NaNO_2/HCl}$ $2,4,6-$Tribromobenzenediazonium chloride $\xrightarrow{H_3PO_2/H_2O}$ Product.

  • A
    Bromobenzene
  • B
    $p-$Bromoaniline
  • C
    $1,3,5-$Tribromobenzene
  • D
    $2,4,6-$Tribromophenol

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Assertion : Benzene diazonium salt on boiling with water forms phenol.
Reason : $C-N$ bond is polar.

Given below are two statements: one is labelled as Assertion $(A)$ and the other is labelled as Reason $(R)$.
Assertion $(A)$: $\alpha$-halocarboxylic acid on reaction with dil. $NH_3$ gives good yield of $\alpha$-amino carboxylic acid whereas the yield of amines is very low when prepared from alkyl halides.
Reason $(R)$: Amino acids exist in zwitter ion form in aqueous medium.
In the light of the above statements,choose the correct answer from the options given below:

In the above chemical reaction,intermediate $X$ and reagent/condition $A$ are:

Aniline reacts with acetaldehyde to form

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Which amine yields $N$-nitroso amine after treatment with nitrous acid $(NaNO_2, HCl)$?

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