If $BaCl_2$ ionizes to an extent of $80 \%$ in aqueous solution, the value of van't Hoff factor is

$12.25 \ g$ of $CH_3CH_2CHClCOOH$ is added to $250 \ g$ of water to make a solution. If the dissociation constant of the above acid is $1.44 \times 10^{-3}$,the depression in the freezing point of water in $^{\circ}C$ is ($K_f$ for water is $1.86 \ K \ kg \ mol^{-1}$)

$2 \ m$ aqueous solution of an electrolyte $X_3Y_2$ is $25\%$ ionized. The boiling point of the solution is .......... $K.$ ($K_b$ for $H_2O = 0.52 \ K \ kg/mol$)

Identify the compound amongst the following whose $0.1 \ M$ aqueous solution has the highest boiling point.

Assuming $100\%$ dissociation of $1 \ m$ $KCl$ solution in water,the freezing point of the solution will be ........ $^oC$. $(K_f = 1.86 \ K \ kg \ mol^{-1})$

$A$ sample of water is found to contain $5.85 \% \left(\frac{w}{w}\right)$ of $AB$ (molecular mass $58.5$) and $9.50 \% \left(\frac{w}{w}\right)$ $XY_2$ (molecular mass $95$). Assuming $80 \%$ ionisation of $AB$ and $60 \%$ ionisation of $XY_2$, the freezing point of the water sample is: [Given, $K_f$ for water $= 1.86 \ K \ kg \ mol^{-1}$, freezing point of pure water $= 273 \ K$ and $A, B, X, Y$ are monovalent ions.] (in $K$)