If standard reduction potentials $(E^0)$ of $(Al^{+3}_{(aq)}|Al(s))$, $(Fe^{+2}_{(aq)}|Fe(s))$, $(Cu^{+2}_{(aq)}|Cu(s))$ and $(Ag^{+1}_{(aq)}|Ag(s))$ are $-1.66 \text{ V}$, $-0.44 \text{ V}$, $+0.34 \text{ V}$ and $+0.79 \text{ V}$ respectively, which of the following reactions is non-spontaneous?

  • A
    $2Ag(s) + Fe^{+2}_{(aq)} \rightarrow 2Ag^{+1}_{(aq)} + Fe(s)$
  • B
    $2Al(s) + 3Cu^{+2}_{(aq)} \rightarrow 2Al^{+3}_{(aq)} + 3Cu(s)$
  • C
    $Fe(s) + Cu^{+2}_{(aq)} \rightarrow Fe^{+2}_{(aq)} + Cu(s)$
  • D
    $2Al(s) + 3Fe^{+2}_{(aq)} \rightarrow 2Al^{+3}_{(aq)} + 3Fe(s)$

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Calculate $E_{\text{cell}}^{\circ}$ for $Cd_{(s)}|Cd^{2+}_{(1M)}||Ag^{+}_{(1M)}|Ag_{(s)}$. Given: $E^{\circ}_{Cd^{2+}/Cd} = -0.403 \ V$ and $E^{\circ}_{Ag^{+}/Ag} = 0.799 \ V$. (in $V$)

Standard electrode potential of $SHE$ at $298 \, K$ is ............. $V$.

$K,$ $Ca,$ and $Li$ metals may be arranged in the increasing order of their standard electrode potentials as

The standard reduction potentials (in $V$) of a few metal ion/metal electrodes are given below: $Cr^{3+}/Cr = -0.74$; $Cu^{2+}/Cu = +0.34$; $Pb^{2+}/Pb = -0.13$; $Ag^{+}/Ag = +0.8$. The reducing strength of the metals follows the order:

The standard reduction potentials at $25^o C$ are given below. Which is the strongest reducing agent?
$Zn^{2+}_{(aq)} + 2e^{-} \rightleftharpoons Zn_{(s)}$,$E^o_{RP} = -0.762 \, V$
$Cr^{3+}_{(aq)} + 3e^{-} \rightleftharpoons Cr_{(s)}$,$E^o_{RP} = -0.740 \, V$
$2H^{+}_{(aq)} + 2e^{-} \rightleftharpoons H_{2(g)}$,$E^o_{RP} = 0.00 \, V$
$Fe^{3+}_{(aq)} + e^{-} \rightleftharpoons Fe^{2+}_{(aq)}$,$E^o_{RP} = 0.77 \, V$

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