If the instantaneous rate of reaction is stated as $-\frac{1}{2} \frac{d[x]}{dt} = -\frac{d[y]}{dt} = \frac{1}{2} \frac{d[z]}{dt}$,identify the reaction.

  • A
    $x + 2y \rightarrow 2z$
  • B
    $2x + y \rightarrow 2z$
  • C
    $x + y \rightarrow z$
  • D
    $2x + 2y \rightarrow z$

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An indicator '$X$' is used for studying the effect of variation in concentration of iodide on the rate of reaction of iodide ion with $H_2O_2$ at room temperature. The indicator '$X$' forms a blue-colored complex with compound '$A$' present in the solution. The indicator '$X$' and compound '$A$' respectively are:

From the concentrations of $C_{4}H_{9}Cl$ (butyl chloride) at different times given below,calculate the average rate of the reaction:
$C_{4}H_{9}Cl + H_{2}O \rightarrow C_{4}H_{9}OH + HCl$
during different intervals of time.
$t/s$ $0$ $50$ $100$ $150$ $200$ $300$ $400$ $700$ $800$
$[C_{4}H_{9}Cl]/mol\ L^{-1}$ $0.100$ $0.0905$ $0.0820$ $0.0741$ $0.0671$ $0.0549$ $0.0439$ $0.0210$ $0.017$

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In a pseudo first order reaction in water,the following results were obtained:
$t / s$ $0$ $30$ $60$ $90$
$[A] / mol \ L^{-1}$ $0.55$ $0.31$ $0.17$ $0.085$

Calculate the average rate of reaction between the time interval $30$ to $60 \ s$.

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For a reaction $\frac{1}{2} A \rightarrow 2 B$,the rate of disappearance of $A$ is related to the rate of appearance of $B$ by the expression:

The decomposition of $N_{2}O_{5}$ in $CCl_{4}$ at $318 \ K$ has been studied by monitoring the concentration of $N_{2}O_{5}$ in the solution. Initially the concentration of $N_{2}O_{5}$ is $2.33 \ mol \ L^{-1}$ and after $184 \ minutes$,it is reduced to $2.08 \ mol \ L^{-1}$. The reaction takes place according to the equation:
$2N_{2}O_{5(g)} \rightarrow 4NO_{2(g)} + O_{2(g)}$
Calculate the average rate of this reaction in terms of hours,minutes,and seconds. What is the rate of production of $NO_{2}$ during this period?

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