In $Fe(CO)_5$,the $Fe-C$ bond has

  • A
    Ionic character
  • B
    $\sigma-$ character only
  • C
    $\pi-$ character only
  • D
    both $\sigma$ and $\pi$ character

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$B$. Due to synergic bonding interactions between metal and $CO$ ligand, the metal-carbon bond becomes weak.
$C$. The metal-carbon $\sigma$ bond is formed by the donation of a lone pair of electrons on the carbonyl carbon into a vacant orbital of metal.
$D$. The metal-carbon $\pi$ bond is formed by the donation of electrons from a filled $d$-orbital of metal into a vacant $\pi^*$ orbital of $CO$.
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The bond length of $C-O$ bond in $CO$ is $1.128 \ \mathring{A}$. The $C-O$ bond length in $Fe(CO)_5$ is ................ $\mathring{A}$.

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