In a closed vessel,the decomposition of solid $Mg(HCO_3)_2$ is given as follows:
$Mg(HCO_3)_{2(s)} \rightleftharpoons MgCO_{3(s)} + CO_{2(g)} + H_2O_{(g)}$
Given $K_p = 64 \ bar^2$ and the mole fraction of $CO_2$ is $0.8$,calculate the total pressure at equilibrium. (in $bar$)

In a vessel of volume $1 \, dm^3$,$1 \, mol$ of $N_2$ and $2 \, mol$ of $H_2$ are taken for the reaction. If $0.8 \, mol$ of $NH_3$ is obtained at equilibrium,the concentration of $H_2$ in the vessel will be .......... $mol \, dm^{-3}$.

Write a relation between $\Delta G$ and $Q$ and define the meaning of each term and answer the following:
$(a)$ Why a reaction proceeds forward when $Q < K$ and no net reaction occurs when $Q = K$.
$(b)$ Explain the effect of increase in pressure in terms of reaction quotient $Q$.
For the reaction: $CO_{(g)} + 3H_{2(g)} \rightleftharpoons CH_{4(g)} + H_{2}O_{(g)}$

If the pressure in a reaction vessel for the following reaction is increased by decreasing the volume,what will happen to the concentrations of $CO$ and $CO_2$ ?
$H_2O_{(g)} + CO_{(g)} \rightleftharpoons H_{2(g)} + CO_{2(g)} + \text{Heat}$

In a $1.0 \, L$ vessel at $90 \, ^\circ C$,$0.2 \, mol$ of $H_{2(g)}$ and $2.0 \, mol$ of $S_{(s)}$ are mixed. For the reaction $H_{2(g)} + S_{(s)} \rightleftharpoons H_2S_{(g)}$; $K_p = 6.8 \times 10^{-2}$,the partial pressure of $H_2S_{(g)}$ at equilibrium will be ............ $atm$.

Given the equilibrium constants for the following reactions:
$(1) \ CO_{2(g)} + H_{2(g)} \rightleftharpoons CO_{(g)} + H_2O_{(g)} \ ; \ K_1$
$(2) \ CO_{(g)} + H_2O_{(g)} \rightleftharpoons CO_{2(g)} + H_{2(g)} \ ; \ K_2$
What is the relationship between $K_1$ and $K_2$?