In collision theory of chemical reaction,$Z_{AB}$ represents

  • A
    the fraction of molecules with energies equal to $E_{a}$
  • B
    the fraction of molecules with energies greater than $E_{a}$
  • C
    the collision frequency of reactants,$A$ and $B$
  • D
    steric factor

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$A$ reaction is catalysed by $X$. Here $X$:

The activation energy of a reaction at a given temperature is found to be $2.303 \ RT \ J \ mol^{-1}$. The ratio of rate constant to the Arrhenius factor is

For the reaction $A_2 + B_2 \rightleftharpoons 2AB$,the activation energies for the forward and backward reactions are $180 \, kJ \, mol^{-1}$ and $200 \, kJ \, mol^{-1}$ respectively. In the presence of a catalyst,the activation energy for both (forward and backward) reactions decreases by $100 \, kJ \, mol^{-1}$. What will be the enthalpy change $(\Delta H)$ for the reaction $(A_2 + B_2 \rightarrow 2AB)$ in the presence of a catalyst in $kJ \, mol^{-1}$?

$A$ reaction takes place in three steps with individual rate constant and activation energy as follows:
$Step$$Rate \ constant$$Activation \ energy$
$Step-1$$k_1$$E_{a1} = 180 \ kJ/mol$
$Step-2$$k_2$$E_{a2} = 80 \ kJ/mol$
$Step-3$$k_3$$E_{a3} = 50 \ kJ/mol$
If overall rate constant,$k = (\frac{k_1 k_2}{k_3})^{2/3}$,then overall activation energy of the reaction will be .......... $kJ/mol$.

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For the gaseous reactions,calculate the approximate value of temperature at which $k_1 = k_2$. $[\ln\, 10 = 2.3]$.
$A \to B$ $k_1 = 10^{15} e^{-25000 / 8.314\, T}$
$C \to D$ $k_2 = 10^{14} e^{-15000 / 8.314\, T}$

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