In the conversion of limestone to lime,$CaCO_{3(s)} \rightarrow CaO_{(s)} + CO_{2(g)}$,the values of $\Delta H^{\circ}$ and $\Delta S^{\circ}$ are $+179.1 \ kJ \ mol^{-1}$ and $160.2 \ J \ K^{-1} \ mol^{-1}$ respectively at $298 \ K$ and $1 \ bar$. Assuming that $\Delta H^{\circ}$ and $\Delta S^{\circ}$ do not change with temperature,the temperature above which the conversion of limestone to lime will be spontaneous is ........... $K$.

  • A
    $1118$
  • B
    $1008$
  • C
    $1200$
  • D
    $845$

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Calculate $\Delta H_f^o$ for $UBr_4$ from the $\Delta G^o$ of reaction and the $S^o$ values: $U_{(s)} + 2Br_2(\ell) \to UBr_{4(s)}$; $\Delta G^o = -788.6 \ kJ$; $S^o \ (J/K \cdot mol): U_{(s)} = 50.3, Br_2(\ell) = 152.3, UBr_{4(s)} = 242.6$.

The dependence of Gibbs free energy on pressure for an isothermal process of an ideal gas is given by:

For the given reaction: $H_{2(g)} + S_{(s)} \to H_2S_{(g)}$; $\Delta H_r = 100\, kJ/mol$ and $\Delta S_r = 400\, J/mol\cdot K$. The temperature at which the above reaction occurs reversibly is (Assuming $\Delta H_r$ and $\Delta S_r$ are independent of temperature) ..... $K$.

Identify from the following the correct set of thermodynamic conditions for the reaction to be spontaneous below equilibrium temperature.

Compare the following criteria for spontaneity of a reaction based on the values of $\Delta_{\text{r}}H^0$,$\Delta_{\text{r}}S^0$,and $\Delta_{\text{r}}G^0$:
$\Delta_{\text{r}}H^0$$\Delta_{\text{r}}S^0$$\Delta_{\text{r}}G^0$Description
$(a) (+)$$(-)$$(+)$$(i) \text{ Non-spontaneous at all temperatures}$
$(b) (-)$$(-)$$(-)$$(ii) \text{ Spontaneous at low temperatures}$
$(c) (-)$$(+)$$(-)$$(iii) \text{ Spontaneous at all temperatures}$

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