In a $1 \, L$ container,the reaction of $2 \, mol$ $N_2$ and $5 \, mol$ $H_2$ occurs. If the equilibrium concentration of $NH_3$ is half the equilibrium concentration of $N_2$,what is the equilibrium constant $(K_c)$?

  • A
    $1.82 \times 10^{-3}$
  • B
    $7.29 \times 10^{-3}$
  • C
    $9.72 \times 10^{-3}$
  • D
    $10.5 \times 10^{-2}$

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$A$ mixture of $1.57 \ mol$ of $N_2$,$1.92 \ mol$ of $H_2$ and $8.13 \ mol$ of $NH_3$ is introduced into a $20 \ L$ reaction vessel at $500 \ K$. At this temperature,the equilibrium constant,$K_c$ for the reaction $N_{2(g)} + 3H_{2(g)} \longleftrightarrow 2NH_{3(g)}$ is $1.7 \times 10^2$. Is the reaction mixture at equilibrium? If not,what is the direction of the net reaction?

For the reaction $N_2 + O_2 \rightleftharpoons 2NO$ at $300 \, ^\circ C$,the value of $K_c$ is $9 \times 10^{-4}$. If equivalent amounts of $N_2$ and $O_2$ are used,what is the concentration of $NO$ at equilibrium (in terms of $a$) (in $, a$)?

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Fill in the blanks:
$a$. If a reaction is in equilibrium,then the rate of the forward reaction and the rate of the backward reaction will be ....... .
$b$. If $\Delta G$ is negative,then thermodynamically the reaction takes place in the ...... direction.
$c$. The equilibrium constant gives ........ information for a reaction.

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Write a relation between $\Delta G$ and $Q$ and define the meaning of each term and answer the following:
$(a)$ Why a reaction proceeds forward when $Q < K$ and no net reaction occurs when $Q = K$.
$(b)$ Explain the effect of increase in pressure in terms of reaction quotient $Q$.
For the reaction: $CO_{(g)} + 3H_{2(g)} \rightleftharpoons CH_{4(g)} + H_{2}O_{(g)}$

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Equilibrium constants for the following reactions are given (pressure in $atm$) for the reactions at $0\,^{\circ}C$. Select the option mentioning the correct order of True $(T)$ or False $(F)$ statements:
$(A) \ A \cdot 6H_2O_{(s)} \rightleftharpoons A \cdot 2H_2O_{(s)} + 4H_2O_{(g)}; \ K_P = 1.6 \times 10^{-11}$
$(B) \ B \cdot 12H_2O_{(s)} \rightleftharpoons B \cdot 7H_2O_{(s)} + 5H_2O_{(g)}; \ K_P = 2.43 \times 10^{-13}$
$(C) \ C \cdot 10H_2O_{(s)} \rightleftharpoons C_{(s)} + 10H_2O_{(g)}; \ K_P = 10^{-30}$
Aqueous tension of $H_2O$ at $0\,^{\circ}C$ is given as $0.76 \ torr$.
$(I)$ The most effective drying agent will be $C_{(s)}$ out of $C_{(s)}$,$B \cdot 7H_2O_{(s)}$,and $A \cdot 2H_2O_{(s)}$.
$(II)$ At $0\,^{\circ}C$,$A \cdot 6H_2O_{(s)}$ and $B \cdot 12H_2O_{(s)}$ will be efflorescent.
$(III)$ If $R.H.$ is less than $100\%$ in a chamber at $0\,^{\circ}C$,then none of the substances can act as deliquescent.

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