In sulphur estimation,$0.471 \ g$ of an organic compound gave $1.4439 \ g$ of barium sulphate. The percentage of sulphur in the compound is $.............$ (Nearest Integer) (Given: Atomic mass $Ba: 137 \ u, S: 32 \ u, O: 16 \ u$)

Given below are two statements :
Statement $I$ : Kjeldahl method is applicable to estimate nitrogen in pyridine.
Statement $II$ : The nitrogen present in pyridine can easily be converted into ammonium sulphate in Kjeldahl method.
In the light of the above statements,choose the correct answer from the options given below.

$x \ mg$ of an organic compound was analysed by the Kjeldahl method. The ammonia evolved was absorbed in $50 \ mL$ of $0.5 \ M \ H_2SO_4$. The unused acid required $60 \ mL$ of $0.5 \ M \ NaOH$ solution for complete neutralization. If the percentage of nitrogen in the compound is $56$,the value of $x$ is:

$0.53 \ g$ of an organic compound $(x)$ when heated with excess of nitric acid (concentrated) and then with silver nitrate gave $0.75 \ g$ of silver bromide precipitate. $1.0 \ g$ of $(x)$ gave $1.32 \ g$ of $CO_2$ gas on combustion. The percentage of hydrogen in the compound $(x)$ is . . . . . . $\%$. [Nearest Integer]
[Given : Molar mass in $g \ mol^{-1} H : 1, C : 12, Br : 80, Ag : 108, O : 16$; Compound $(x) : C_xH_yBr_z$] (in $\%$)

An organic compound is subjected to chlorination to get compound $A$. When $0.5 \ g$ of compound $A$ is reacted with $AgNO_3$ [Carius Method],it forms $0.3849 \ g$ of $AgCl$. Calculate the percentage of chlorine in compound $A$. (Round off to the nearest integer)
(Atomic masses of $Ag$ and $Cl$ are $107.87$ and $35.5$ respectively)

The element whose percentage composition in an organic compound can be determined by the Carius method is