In the wet tests for identification of various cations by precipitation,which transition element cation does not belong to group $IV$ in qualitative inorganic analysis?

$A$ (Orange color compound) $\xrightarrow{(B) + \text{conc. } H_2SO_4}$ $C$ (Red gas) $\xrightarrow{NaOH + AgNO_3}$ $D$ (Red ppt.) $\xrightarrow{\text{NH}_3 \text{ solution}}$ Yellow solution.
$B$ $\xrightarrow[\Delta]{NaOH}$ $F \uparrow$ (Gives white fumes with $HCl$).
Identify $B$ and $F$ respectively :-

$(T)$ imparts violet colour $\xrightarrow{compd.\,(U) + conc.\,H_2SO_4}$ $(V)$ Red gas $\xrightarrow{NaOH + AgNO_3}$ $(W)$ Red ppt. $\xrightarrow{NH_3\,soln.}$ $(X)$
$(W)$ Red ppt. $\xrightarrow{dil.\,HCl}$ $(Y)$ white ppt.
$(U)$ $\xrightarrow[\Delta]{NaOH}$ $(Z)$ gas (gives white fumes with $HCl$)?
$(T)$ sublimes on heating
Identify $(T)$ to $(Z).$

Which of the following match is $INCORRECT$ :

In which of the following is $NH_{3}$ not used?

The colour of the precipitate produced by adding $NaOH$ solution to $HgCl_2$ is