In which one of the following conversions is phosphorus pentachloride $(PCl_5)$ used as a reagent?

  • A
    $H_2C=CH_2 \to CH_3CH_2Cl$
  • B
    $CH_3-O-CH_3 \to CH_3Cl$
  • C
    $CH_3CH_2OH \to CH_3CH_2Cl$
  • D
    Both $(b)$ and $(c)$

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Match the items given in column $-I$ with the items given in column $-II$.
column $-I$ column $-II$
$(A)$ Antifreeze used in car engine $(1)$ Neutral $FeCl_3$
$(B)$ Solvent used in perfumes $(2)$ Glycerol
$(C)$ Starting material for picric acid $(3)$ Methanol
$(D)$ Wood spirit $(4)$ Phenol
$(E)$ Reagent used for detection of phenolic group $(5)$ Ethylene glycol
$(F)$ By-product of soap industry used in cosmetics $(6)$ Ethanol

Match List-$I$ with List-$II$.
Choose the correct answer from the options given below:

Match the columns:
Column-$I$Column-$II$
$A$. Methanol$p$. Conversion of phenol to salicylic acid
$B$. Kolbe's reaction$q$. Wood spirit
$C$. Williamson's reaction$r$. Vapours are passed over heated copper at $573 \ K$
$D$. Conversion of $2^\circ$ alcohol to ketone$s$. Reaction of alkyl halide with sodium alkoxide

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Match List-$I$ with List-$II$ :
List-$I$ List-$II$
$A$. $H_{3}C-CH(OH)-CH_{3}$ $I$. $(i)$ oleum; (ii) $NaOH, \Delta$; (iii) $H^{+}$
$B$. $CH_{3}COOH \rightarrow CH_{3}CH_{2}OH$ $II$. $(i)$ $O_{2}$; (ii) $H_{2}O/H^{+}$
$C$. $CH_{3}CH_{2}OH \rightarrow H_{3}C-CH(OH)-CH_{3}$ $III$. $(i)$ $CH_{3}OH, H^{+}$; (ii) $H_{2}$, Catalyst
$D$. Benzene $\rightarrow$ Phenol $IV$. $(i)$ conc. $H_{2}SO_{4}, \Delta$; (ii) $H^{+}/H_{2}O$

Choose the correct answer from the options given below :

If the starting material is $1-$methyl$-1,2-$epoxycyclopentane,determine which compound correctly represents the product of its reaction with sodium methoxide in methanol.

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