Match List-$I$ with List-$II$.
List-$I$ (Industrial process) List-$II$ (Application)
$(a)$ Haber's process $(i)$ $HNO_{3}$ synthesis
$(b)$ Ostwald's process $(ii)$ Aluminium extraction
$(c)$ Contact process $(iii)$ $NH_{3}$ synthesis
$(d)$ Hall-Heroult process $(iv)$ $H_{2}SO_{4}$ synthesis

Choose the correct answer from the options given below:

  • A
    $(a-ii, b-iii, c-iv, d-i)$
  • B
    $(a-iii, b-iv, c-i, d-ii)$
  • C
    $(a-iii, b-i, c-iv, d-ii)$
  • D
    $(a-iv, b-i, c-ii, d-iii)$

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Extraction of copper from copper pyrite $CuFeS_2$ involves:
$A$. Crushing followed by concentration of the ore by froth-flotation
$B$. Removal of iron as slag
$C$. Self-reduction step to produce 'blister copper' following evolution of $SO_2$
$D$. Refining of 'blister copper' by carbon reduction

Consider the following:
Statement-$I$ : In the extraction of $Al$ by Hall-Heroult process,pure $Al_2O_3$ mixed with $Na_3AlF_6$ lowers its melting point and increases conductivity.
Statement-$II$ : Zirconium metal is purified by zone refining method.

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